This seems to have been removed at some point. It doesn't work for me any more, but it definitely did before.
Edit: Ah, I've manually disabled it in PowerToy's keyboard manager.
Fair enough. I just like it when I'm typing and realize my outlook isn't open and the desktop is covered in windows. Even 3 screens doesn't help this problem sometimes haha.
FWIW, there are a few of those that are useful: W is word, E is excel, and I'd bet that the rest of office each has one as well... those are the only two I use regularly 🤷♂️