Itll be interesting to see the results once the samples are brought back next decade. I hope we can make mars a "national park" so we don't screw with it too much.
Curiously, only L-amino acids were detected. Did they test for D-aa and didn't see any, or did they test for L-aa only? The paper doesn't say. If the former, that's a pretty big deal. As far as I know there is no inorganic process that can produce non-racemic chiral molecules.
Ah! This reference paper goes into more detail about how the reference spectra for the Raman fluorescence were acquired: https://doi.org/10.1089/ast.2022.0023 They built a fluorescence spectrometer identical to the SHERLOC tool onboard the Perseverance rover on Mars and tested it against a library of molecules of interest, including all L-amino acids and a few of the D-amino acids. Turns out the spectrometer cannot differentiate between the two:
The fluorescence spectra of d-phenylalanine and l-phenylalanine were almost identical, showing no obvious dependence on the chirality of the α-carbon.